Theory of Valence Transition

Valence-bond theory of compounds of transition metals.

An equation relating the strength (bondforming power) of an spd hybrid bond orbital to the angles it makes with other bond orbitals is formulated and applied in the discussion of the structures of transition-metal carbonyls and other substances by the valence-bond method. The rather simple theory gives results that agree well with those obtained by the complicated and laborious calculation of s...

Elastic-Plastic Transition of Pressurized Functionally Graded Orthotropic Cylinder using Seth’s Transition Theory

In this paper the radial deformation and the corresponding stresses in a functionally graded orthotropic hollow cylinder with the variation in thickness and density according to power law and rotating about its axis under pressure is investigated by using Seth's transition theory. The material of the cylinder is assumed to be non-homogeneous and orthotropic. This theory helps to achieve better ...

Avoided valence transition in a plutonium superconductor.

The d and f electrons in correlated metals are often neither fully localized around their host nuclei nor fully itinerant. This localized/itinerant duality underlies the correlated electronic states of the high-Tc cuprate superconductors and the heavy-fermion intermetallics and is nowhere more apparent than in the 5f valence electrons of plutonium. Here, we report the full set of symmetry-resol...

Magnetic-field control of quantum critical points of valence transition.

We study the mechanism of how critical end points of first-order valence transitions are controlled by a magnetic field. We show that the critical temperature is suppressed to be a quantum critical point (QCP) by a magnetic field, and unexpectedly, the QCP exhibits nonmonotonic field dependence in the ground-state phase diagram, giving rise to the emergence of metamagnetism even in the intermed...

A chemist's guide to valence bond theory